T. Coussaert et M. Baus, MAKING A (COLLOIDAL) LIQUID - A VAN-DER-WAALS APPROACH, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(1), 1995, pp. 862-869
The relation between the nature of the phase diagram and the pair pote
ntial is investigated on the basis of a recently introduced van der Wa
als theory. Both simple fluids and colloidal dispersions that admit a
simple fluid description are considered. A necessary and sufficient co
ndition for the occurrence of a liquid phase is formulated and studied
for four specific cases. The results compare favorably with data obta
ined from other sources.