Semiconducting polymer heterostructures with strong two-dimensional qu
antum confinement of excitons are prepared by self-assembly of two con
jugated polymers in binary, blends. Exciton confinement effects in the
semiconducting polymer quantum wires were observed at room temperatur
e by photoluminescence excitation and photoluminescence spectroscopies
and by electric field-induced photoluminescence quenching. Observatio
n of new exciton states, enhanced luminescence, and stability of lumin
escence at high electric fields (3 x 10(6) V/cm) confirmed the one-dim
ensionality of the excitons in the organic quantum wires. (C) 1997 Ame
rican Institute of Physics.