X-ray diffraction was used to characterize the dependence of mean crys
tallite size and crystallinity on the thickness of coatings. A fall in
mean crystallite size but a rise in crystallinity with increased thic
kness was observed. The reason might be due to the differences in cool
ing rate of partially molten particles of hydroxyapatite. The thicker
the coating, the longer the cooling time. The longer cooling time was
beneficial to the occurrence of recrystallization. It was found that t
he critical thickness of recrystallization (r(c)) was about 20 mu m.