It is expected that during the impact of a cluster ion with a surface
the interactions among the participating atoms will create transient c
onditions that are more extreme than those found for the impacts of in
dividual atoms. At energies of keV per atom molecular dynamics simulat
ions suggest a variety of experimental observations that may provide d
iagnostic information about the impact. Among the phenomena predicted
are: an enhanced probability for the rebound (''splash'') of energetic
atoms from the projectile; the emission of sharp-line Auger electrons
well below their kinematic threshold due to collisions among the movi
ng atoms; the existence of highly excited rebounding projectile fragme
nts that decay by thermionic electron emission and fragmentation/fissi
on. MeV cluster beams (e.g., C-n(+), Au-n(+)) are now available, which
also offer a potentially rich variety of new phenomena. For them the
cooperative effect of the associated atoms in the cluster for electron
ic excitation and nuclear recoil may produce extreme conditions both a
t the point of impact and along the cluster ''track'' in the target. T
his talk will review to what extent such effects have been observed al
ready, the optimum choices for future experiments, and the relation of
the observations to the conditions during the cluster impact.