MACROCYCLIC DITHIOMALEONITRILE DERIVATIVES CONTAINING SULFUR AND NITROGEN HETEROATOMS

Citation
Sj. Lange et al., MACROCYCLIC DITHIOMALEONITRILE DERIVATIVES CONTAINING SULFUR AND NITROGEN HETEROATOMS, Tetrahedron, 51(30), 1995, pp. 8175-8188
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
51
Issue
30
Year of publication
1995
Pages
8175 - 8188
Database
ISI
SICI code
0040-4020(1995)51:30<8175:MDDCSA>2.0.ZU;2-A
Abstract
A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen, and nitrogen heteroa toms is presented along with the single-crystal X-ray structures of th e thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines c apable of coordinating multiple metal ions.