STUDIES OF AU(I) COMPLEXES WITH TRIPHENYLPHOSPHINE AND PERFLUORINATEDCARBOXYLATES

Citation
E. Szlyk et al., STUDIES OF AU(I) COMPLEXES WITH TRIPHENYLPHOSPHINE AND PERFLUORINATEDCARBOXYLATES, Polish Journal of Chemistry, 69(8), 1995, pp. 1103-1108
Citations number
19
Categorie Soggetti
Chemistry
Journal title
ISSN journal
01375083
Volume
69
Issue
8
Year of publication
1995
Pages
1103 - 1108
Database
ISI
SICI code
0137-5083(1995)69:8<1103:SOACWT>2.0.ZU;2-L
Abstract
A series of new gold(I) complexes with triphenylphosphine and perfluor inated carboxylic acids were synthesized and their thermal and spectro scopic (IR, C-13, F-19, P-31 NMR) properties studied Au(I) appears to be two coordinated by triphenylphosphine and unidentately bonded carbo xylates. Thermal decomposition proceeds in several steps and leads to metallic gold.