DIFFERENT PATHWAYS OF THE REACTION OF INCL WITH PH(3)PAUCL - ISOLATION OF THE FIRST MIXED-VALENT MIXED-METAL GOLD INDIUM CLUSTER/

Authors
GABBAI FP SCHIER A RIEDE J SCHMIDBAUR H
Citation
Fp. Gabbai et al., DIFFERENT PATHWAYS OF THE REACTION OF INCL WITH PH(3)PAUCL - ISOLATION OF THE FIRST MIXED-VALENT MIXED-METAL GOLD INDIUM CLUSTER/, Inorganic chemistry, 34(15), 1995, pp. 3855-3856
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
15
Year of publication
1995
Pages
3855 - 3856
Database
ISI
SICI code
0020-1669(1995)34:15<3855:DPOTRO>2.0.ZU;2-G
Abstract
In the absence of an auxiliary ligand, the title reaction led to redox products among which In2Cl4(thf)(2) has been identified as an In-In-b onded dinuclear In(II) complex. However, in the presence of Ph(2)PCH(2 )CH(2)PPh(2) (dppe), a novel hexanuclear cluster of the formula Au3In3 Cl6(dppe)(2) was produced, which is composed of a triangle of gold ato ms (with one very short edge) penetrated by a perpendicular triangle o f indium atoms.