CHIRAL [RU(PP)(2)(CO)(2)](2-BRIDGED DINUCLEAR COMPLEXES() SPECIES (PP=BIDENTATE POLYPYRIDYL LIGAND) AND THEIR USE IN THE STEREOSELECTIVE SYNTHESIS OF LIGAND)

Authors
RUTHERFORD TJ QUAGLIOTTO MG KEENE FR
Citation
Tj. Rutherford et al., CHIRAL [RU(PP)(2)(CO)(2)](2-BRIDGED DINUCLEAR COMPLEXES() SPECIES (PP=BIDENTATE POLYPYRIDYL LIGAND) AND THEIR USE IN THE STEREOSELECTIVE SYNTHESIS OF LIGAND), Inorganic chemistry, 34(15), 1995, pp. 3857-3858
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
15
Year of publication
1995
Pages
3857 - 3858
Database
ISI
SICI code
0020-1669(1995)34:15<3857:C[DCS(>2.0.ZU;2-4
Abstract
The decarbonylation of chiral [Ru(pp)(2)(CO)(2)](2+) (pp = bidentate p olypyridyl ligands) in the presence of excess pp shows stereoretention in the [Ru(pp)(3)](2+) product, and under the same conditions, its re action with chiral [Ru(pp')(2)(BL)](2+) centers (pp and pp' may or may not be identical; BL = bridging ligand) allows synthesis of specific diastereoisomeric forms of the dinuclear species [(pp)(2)Ru(BL)Ru(pp') (2)](4+).