MECHANISMS FOR THE THERMAL-DECOMPOSITION OF NH4VO3 INTO V6O13, V3O7 AND V2O5

Authors
LAMPEONNERUD C THOMAS JO
Citation
C. Lampeonnerud et Jo. Thomas, MECHANISMS FOR THE THERMAL-DECOMPOSITION OF NH4VO3 INTO V6O13, V3O7 AND V2O5, Journal of materials chemistry, 5(7), 1995, pp. 1075-1080
Citations number
16
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
5
Issue
7
Year of publication
1995
Pages
1075 - 1080
Database
ISI
SICI code
0959-9428(1995)5:7<1075:MFTTON>2.0.ZU;2-8
Abstract
The thermal decomposition of ammonium metavanadate, NH4VO3, has been s tudied by differential scanning calorimetry (DSC), mass spectrometry ( MS) and X-ray diffraction (XRD) in the temperature range 50-500 degree s C. Different experimental conditions (heating rate and atmosphere) h ave been explored in various combinations. Different types of reaction mechanisms leading to crystalline V6O13 and V3O7 can be identified. T he formation of V2O5 is also discussed briefly.