INCREMENTAL RIGIDIFICATION OF A FOLDABLE ANION HOST - DOES IT HELP INGUEST BINDING

Authors
PESCHKE W SCHMIDTCHEN FP
Citation
W. Peschke et Fp. Schmidtchen, INCREMENTAL RIGIDIFICATION OF A FOLDABLE ANION HOST - DOES IT HELP INGUEST BINDING, Tetrahedron letters, 36(29), 1995, pp. 5155-5158
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
29
Year of publication
1995
Pages
5155 - 5158
Database
ISI
SICI code
0040-4039(1995)36:29<5155:IROAFA>2.0.ZU;2-W
Abstract
In an effort to quantify the effect of freezing internal rotations in foldable onion hosts we prepared compounds 11-14. In spite of their st ructural similarity the complex stability in this series with squarate anion in DMSO spanned about two powers of ten and gave no indication for a dependence on host flexibility.