LEWIS ACID-CATALYZED COUPLING REACTIONS OF ALLYL TRIMETHYLSILYL ETHERS WITH ALLYLSILANES

Authors
YOKOZAWA T FURUHASHI K NATSUME H
Citation
T. Yokozawa et al., LEWIS ACID-CATALYZED COUPLING REACTIONS OF ALLYL TRIMETHYLSILYL ETHERS WITH ALLYLSILANES, Tetrahedron letters, 36(29), 1995, pp. 5243-5246
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
29
Year of publication
1995
Pages
5243 - 5246
Database
ISI
SICI code
0040-4039(1995)36:29<5243:LACROA>2.0.ZU;2-#
Abstract
For the simultaneous preparation of molecules having both the nucleoph ilic and electrophilic sites, allyl trimethylsilyl ethers as electroph ilic allylating reagents are studied. Allyl trimethylsilyl ethers reac t with allyl trimethylsilanes in the presence of a catalytic amount of ZnCl2 at room temperature to afford the corresponding 1,5-dienes in g ood yields.