ENANTIOSELECTIVE TOTAL SYNTHETIC ROUTE TO (-APHIDICOLIN())

Authors
TOYOTA M NISHIKAWA Y FUKUMOTO K
Citation
M. Toyota et al., ENANTIOSELECTIVE TOTAL SYNTHETIC ROUTE TO (-APHIDICOLIN()), Tetrahedron letters, 36(30), 1995, pp. 5379-5382
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
30
Year of publication
1995
Pages
5379 - 5382
Database
ISI
SICI code
0040-4039(1995)36:30<5379:ETSRT(>2.0.ZU;2-8
Abstract
Enantioselective total synthetic route to (+)-aphidicolin (1) has been described. Cycloisomerization reaction (9-->10) and intramolecular Di els-Alder reaction (12-->13) were employed for the key steps of the se quence.