DEPROTECTION OF CARBOXYLIC-ACIDS FROM THEIR PHENACYL ESTERS BY CU(II)O-2/DMF-H2O - UNUSUAL FORMATION OF BENZALDEHYDE FROM THE PHENACYL GROUP/

Authors
RAM RN SINGH L
Citation
Rn. Ram et L. Singh, DEPROTECTION OF CARBOXYLIC-ACIDS FROM THEIR PHENACYL ESTERS BY CU(II)O-2/DMF-H2O - UNUSUAL FORMATION OF BENZALDEHYDE FROM THE PHENACYL GROUP/, Tetrahedron letters, 36(30), 1995, pp. 5401-5404
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
30
Year of publication
1995
Pages
5401 - 5404
Database
ISI
SICI code
0040-4039(1995)36:30<5401:DOCFTP>2.0.ZU;2-Q
Abstract
Phenacyl esters gave the deprotected carboxylic acids, alongwith PhCO( 2)H, PhCHO and CO2 on heating with CuCl2 or CuSO4 in aqueous DMF (50% v/v) at reflux with continuous bubbling of O-2.