MASS-SPECTROMETRIC STUDY OF SOME ZIRCONOCENE AND HAFNOCENE DIADAMANTANOLATES

Citation
Av. Grafov et al., MASS-SPECTROMETRIC STUDY OF SOME ZIRCONOCENE AND HAFNOCENE DIADAMANTANOLATES, Rapid communications in mass spectrometry, 9(9), 1995, pp. 788-794
Citations number
8
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
ISSN journal
09514198
Volume
9
Issue
9
Year of publication
1995
Pages
788 - 794
Database
ISI
SICI code
0951-4198(1995)9:9<788:MSOSZA>2.0.ZU;2-T
Abstract
The electron ionization mass spectrometric behaviour of a new series o f hafnocene and zirconocene diadamantanolates is discussed. They are a lso compared on the basis of mass-analyzed ion kinetic energy spectrom etry. Fragmentation patterns of the complexes in question give relevan t information on their gas-phase behaviour as MO(2)/MC (M=Zr, Hf) prec ursors for metal-organic chemical vapour deposition.