TRANSITION-STATE RESONANCES IN COLLINEAR (H-, H-2) COLLISIONS

Authors
MAHAPATRA S SATHYAMURTHY N KUMAR S GIANTURCO FA
Citation
S. Mahapatra et al., TRANSITION-STATE RESONANCES IN COLLINEAR (H-, H-2) COLLISIONS, Chemical physics letters, 241(3), 1995, pp. 223-228
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
241
Issue
3
Year of publication
1995
Pages
223 - 228
Database
ISI
SICI code
0009-2614(1995)241:3<223:TRIC(H>2.0.ZU;2-Y
Abstract
The possibility of reactive scattering resonances in collinear (H-, H- 2) collisions is examined by computing the transition state spectra ob tained by Fourier transforming temporal autocorrelation functions for wavepackets placed initially in the transition state region of the ab initio potential energy surface for the system. The nature of the reso nances is investigated by computing the corresponding eigenfunctions a nd their lifetimes.