DETERMINATION OF KINETIC-PARAMETERS OF INORGANIC METALPORPHYRINS

Authors
QU LY MA RH CHEN YG CHEN Y LIU CT
Citation
Ly. Qu et al., DETERMINATION OF KINETIC-PARAMETERS OF INORGANIC METALPORPHYRINS, Journal of thermal analysis, 45(1-2), 1995, pp. 275-287
Citations number
8
Categorie Soggetti
Chemistry Analytical
Journal title
Journal of thermal analysis → ACNP
ISSN journal
03684466
Volume
45
Issue
1-2
Year of publication
1995
Pages
275 - 287
Database
ISI
SICI code
0368-4466(1995)45:1-2<275:DOKOIM>2.0.ZU;2-Z
Abstract
The thermal properties of four heteropoly complexes alpha-K3H3[SiW11Ni (H2O)O-39]. 11.5H(2)O (I), alpha-K3H2[SiW11Fe(H2O)O-39]. 9H(2)O (II), alpha-[(C4H9)(4)N]H-3.5(1.5)[SiW11Fe(H2O)O-39]. 4.5H(2)O (III) and alp ha-[(C4H9)(4)N]H-3.5(2.5)[SiW11Cu(H2O)O-39]. 6H(2)O (IV) were studied by means of TG, DTA and DSC. The activation energy and reaction order of the thermal decomposition reaction of these complexes have been cal culated.