INFLUENCE OF THE PREPARATION PROCESS ON THE CATION-TRANSPORT PROPERTIES OF LI(4-X)O(4) (M=B, AL) SOLID ELECTROLYTES(X)M(X)SI(1)

Authors
MASQUELIER C TABUCHI M TAKEUCHI T SOIZUMI W KAGEYAMA H NAKAMURA O
Citation
C. Masquelier et al., INFLUENCE OF THE PREPARATION PROCESS ON THE CATION-TRANSPORT PROPERTIES OF LI(4-X)O(4) (M=B, AL) SOLID ELECTROLYTES(X)M(X)SI(1), Solid state ionics, 79, 1995, pp. 98-105
Citations number
20
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
79
Year of publication
1995
Pages
98 - 105
Database
ISI
SICI code
0167-2738(1995)79:<98:IOTPPO>2.0.ZU;2-2
Abstract
Recent reinvestigations of the crystal chemistry of Li4SiO4-based soli d solutions Li(4+x)M(x)Si(1-x)O(4) (M = B, Al) are presented in this p aper. The starting lithium salts used (LiOH . H2O or Li2CO3) and the a tmosphere (air, argon) in which the thermal treatments are carried out , play a major role in impurity formation. The influence of Li2CO3 and /or remaining unreacted LiOH on the cation transport properties of Li4 SiO4-based materials is discussed.