LONG-CHAIN (POLYFLUOROALKYL)OXACARBENES

Authors
MOSS RA GE CS
Citation
Ra. Moss et Cs. Ge, LONG-CHAIN (POLYFLUOROALKYL)OXACARBENES, Journal of fluorine chemistry, 73(1), 1995, pp. 101-105
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
73
Issue
1
Year of publication
1995
Pages
101 - 105
Database
ISI
SICI code
0022-1139(1995)73:1<101:L(>2.0.ZU;2-C
Abstract
3-Chloro-3-(1H,1H-pentadecafluorooctoxy)diazirine (7a) and 3,3-bis(1H, 1H-pentadecafluorooctoxy)diazirine (8) have been prepared via several steps from 1H,1H-pentadecafluorooctanol (3). Photolysis or thermolysis of these diazirines generated the corresponding carbenes (1 or 2), wh ich underwent intermolecular reactions with HCl, alcohol 3 and acrylon itrile.