We have investigated the photo-modulated reflection spectra of GaAs qu
antum wells where the top barrier is confined by thin Al0.3Ga0.7As lay
ers. The optical transitions spectra of the first heavy hole hh1 and t
he first light hole lh1 states to the first electron sublevel e1 are o
bserved. Due to the increase of the confinement potential in the near-
surface quantum well by varying the Al0.3Ga0.7As top barrier thickness
, we observe a significant blue-shift of the transition lines (hh1 to
e1 and lh1 to e1) compared to the transition lines of the quantum well
with a thick semiconductor barrier. The experimental observation on t
he energy shift and the variation of the strength ratio between the tr
ansitions e1-hh1 and e1-lh1 can be modeled by a rectangular well combi
ned with a vacuum potential and built-in field.