ALPHA-FLUORINATION OF SULFOXIDES BEARING ALPHA-HYDROGENS BY MOLECULARFLUORINE - A NOVEL METHOD FOR THE SYNTHESIS OF ALPHA-FLUOROSULFONES

Authors
CHIBA J SUGIHARA T KANEKO C
Citation
J. Chiba et al., ALPHA-FLUORINATION OF SULFOXIDES BEARING ALPHA-HYDROGENS BY MOLECULARFLUORINE - A NOVEL METHOD FOR THE SYNTHESIS OF ALPHA-FLUOROSULFONES, Chemistry Letters, (7), 1995, pp. 581-582
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1995
Pages
581 - 582
Database
ISI
SICI code
0366-7022(1995):7<581:AOSBAB>2.0.ZU;2-O
Abstract
Direct formation of alpha-fluorosulfones from sulfoxides bearing alpha -hydrogens merely by reacting molecular fluorine (5% F-2/N-2) is repor ted and a possible mechanism for this novel alpha-fluorination reactio n is proposed.