ADSORPTION AND DIMER FORMATION OF NITROGEN MONOXIDE ON PT(111) AT LOW-TEMPERATURE

Authors
YOSHINOBU J KAWAI M
Citation
J. Yoshinobu et M. Kawai, ADSORPTION AND DIMER FORMATION OF NITROGEN MONOXIDE ON PT(111) AT LOW-TEMPERATURE, Chemistry Letters, (7), 1995, pp. 605-606
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1995
Pages
605 - 606
Database
ISI
SICI code
0366-7022(1995):7<605:AADFON>2.0.ZU;2-1
Abstract
Adsorption and thermal reaction of NO on Pt(111) at temperatures from 25 K to 80 K have been studied by means of infrared reflection absorpt ion spectroscopy. The physisorbed NO molecules form (NO)(2) species on the chemisorbed NO at low temperatures. There are at least two kinds of (NO)(2) species. The dimer species are decomposed into NO, which im mediately desorbs above similar to 40 K. The remaining predominant spe cies after 80 K heating is on-top linear NO species.