THE VISIBLE EXCITATION SPECTRUM OF JET-COOLED NO2 - THE CHAOTIC BEHAVIOR OF A SET OF B-2(2) VIBRONIC LEVELS

We have observed a set of 350 B-2(2) vibronic levels of NO2 in the 16 000-19 360 cm(-1) energy range by the laser induced fluorescence (LIF) technique combined with a supersonic jet. This work extends (i.e., a larger energy range) and improves (i.e., a better detection threshold) our previous study [J. Chem. Phys. 95, 5701 (1991)]. 42 new B-2(2) vi bronic levels have been detected in this range where 159 vibronic leve ls were previously observed. In the 16 580-19 360 cm(-1) energy range we estimate that the 315 observed levels represent 96% of the existing 2B, levels. The correlation properties of this large and almost compl ete set of 315 B-2(2) vibronic levels have been analyzed. We present t he next neighbor distribution, the Sigma(2)(L), and Delta(3)(L) statis tics, the Fourier transform (FT) of the stick spectrum with constant i ntensities (\FT\(2)), and the intensity distribution. The results ofth ese analyses confirm the chaotic behavior of the B-2(2) vibronic level s in this energy range: there are strong level repulsion, long range c orrelations and a Porter-Thomas intensity distribution. The correlatio n ''hole'' observed in the \FT\(2) of the stick vibronic spectrum is c lose to the one of the Gaussian orthogonal ensemble (GOE). However we have found a significant deviation from completely chaotic behavior (G OE type). Two peaks in the FT indicate recurrences (periods of 50 and 150 fs) i.e., periodic motions. We conclude that chaos is established within the B-2(2) vibronic levels of NO2, after few hundred femtosecon ds. (C) 1995 American Institute of Physics.