EXTENSION OF GAUSSIAN-2 (G2) THEORY TO BROMINE-CONTAINING AND IODINE-CONTAINING MOLECULES - USE OF EFFECTIVE CORE POTENTIALS

Basis sets have been developed for carrying out G2 calculations on bro mine- and iodine-containing molecules using all-electron (AE) calculat ions and quasirelativistic energy-adjusted spin-orbit-averaged seven-v alence-electron effective core potentials (ECPs). Out recommended proc edure for calculating G2[ECP] energies for such systems involves the s tandard G2 steps introduced by Pople and co-workers, together with the following modifications: (i) second-order Moller-Plesset (MP2) geomet ry optimizations use polarized split-valence [31,31,1] basis sets for bromine and iodine together with 6-31G(d) for first- and second-row at oms; (ii) single-point higher-level energies are calculated for these geometries using our new supplemented bromine and iodine valence basis sets along with supplemented 6-311G and McLean-Chandler 6-311G bases for first- and second-row atoms, respectively; and (iii) first-order s pin-orbit corrections are explicitly taken into account. An assessment of the results obtained using such a procedure is presented. The resu lts are also compared with corresponding all-electron calculations. We find that the G2[ECP] calculations give results which are generally c omparable in accuracy to those of the G2[AE] calculations but which in volve considerably lower computational cost. They are therefore potent ially useful for larger bromine- and iodine-containing molecules for w hich G2[AE] calculations would not be feasible. (C) 1995 American Inst itute of Physics.