PRODUCTION PLATE OF TITANIUM BY REDUCTION OF TITANIUM TETRACHLORIDE WITH MAGNESIUM

Citation
S. Shimosaki et M. Kuramoto, PRODUCTION PLATE OF TITANIUM BY REDUCTION OF TITANIUM TETRACHLORIDE WITH MAGNESIUM, Kagaku kogaku ronbunshu, 21(4), 1995, pp. 740-745
Citations number
7
Categorie Soggetti
Engineering, Chemical
Journal title
ISSN journal
0386216X
Volume
21
Issue
4
Year of publication
1995
Pages
740 - 745
Database
ISI
SICI code
0386-216X(1995)21:4<740:PPOTBR>2.0.ZU;2-V
Abstract
The reaction rate of the reduction of TiCl4, with Mg was studied by me ans of an impulse response method. In the case of gaseous TiCl4, feed, the reaction rate was proportional to the concentration of TiCl4, and the apparent activation energy was obtained as 59 kJ . mol(-1). In th e case where liquid TiCl4 was fed onto the molten Mg, TiCl4, was vapor ized and then reacted with Mg. The reaction was found to be controlled by the vaporization process of TiCl4. Therefore, the production rate of Ti can be increased by improvement of the vaporization process.