The overlapped glow peaks of CaF2:Mn (with the composition of the main
glow peak around 260 degrees C) become distinguishable through a seri
es of high-level irradiations. Our investigation revealed the fact tha
t the main glow peak consists of three closely approximate peaks, deno
ted as P-2, P-3 and P-4. These three peaks together with P-1, which ap
pears only under high exposures, constitute the main TL spectrum from
room temperature to 350 degrees C. The P-2 is believed to be related t
o the electron trap defect, F-A center, and contributes to approx. 90%
of the cooled optically stimulated luminescence (COSL) response. The
other peaks are made by hole trap defects; modified V-K centers and/or
the oxidation of Mn2+ to Mn3+. The temperature shift between the TL s
ignal and its corresponding PTTL signal is a consequence of the absenc
e of P-2 after u.v. irradiation. The absence of P-2 is a result of the
further phototransfer from P-2, to the lower temperature peak, which
is unstable above room temperature rather than insensitive to u.v. irr
adiation. A plausible COSL mechanism is also presented in this investi
gation.