SYNTHESIS OF FERRIC COORDINATION COMPOUND OF BIS (6-O-M-CARBONYL BENZENESULFONYL)-BETA-CYLODEXTRIN WITH CATALYSIS OF OXIDOREDUCTASE

Authors
DING ZG LIU XQ ZHAN GQ GU YD YANG XD
Citation
Zg. Ding et al., SYNTHESIS OF FERRIC COORDINATION COMPOUND OF BIS (6-O-M-CARBONYL BENZENESULFONYL)-BETA-CYLODEXTRIN WITH CATALYSIS OF OXIDOREDUCTASE, Huaxue xuebao, 53(6), 1995, pp. 578-582
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
53
Issue
6
Year of publication
1995
Pages
578 - 582
Database
ISI
SICI code
0567-7351(1995)53:6<578:SOFCCO>2.0.ZU;2-8
Abstract
As beta-cyclodextrin reacted with m-carbonyl benzenesulfonyl chloride in solution of pyridine at 80 degrees C, bis(6-O-m-carbonyl benzenesul fonyl)-beta-cyclodextrin, which was characterized by H-1-C-13 NMR, IR spectra and elemental analysis, was obtained. The ferric coordination compound of this new product could effectively catalyse benzal alcohol oxidized into benzaldehyde and benzoic acid. The catalytic rate was 1 .4x 10(4) times as much as that FeCl3 catalysing the same reaction.