THE PSEUDOCALANOLIDES - STRUCTURE REVISION OF CALANOLIDE-C AND CALANOLIDE-D

Authors
MCKEE TC CARDELLINA JH DREYER GB BOYD MR
Citation
Tc. Mckee et al., THE PSEUDOCALANOLIDES - STRUCTURE REVISION OF CALANOLIDE-C AND CALANOLIDE-D, Journal of natural products, 58(6), 1995, pp. 916-920
Citations number
8
Categorie Soggetti
Chemistry,"Plant Sciences","Pharmacology & Pharmacy
Journal title
Journal of natural products → ACNP
ISSN journal
01633864
Volume
58
Issue
6
Year of publication
1995
Pages
916 - 920
Database
ISI
SICI code
0163-3864(1995)58:6<916:TP-SRO>2.0.ZU;2-U
Abstract
Nmr spectra of synthetic structures corresponding to those initially r eported for natural compounds calanolide C[1] and calanolide D[2] show ed some subtle differences from those of the natural products. Further analysis has resulted in revision of the structures of the natural co mpounds, now renamed pseudocalanolides C[3] and D[4]. The absolute ste reochemistry of pseudocalanolide C was established as [6S,7S,8R] using the modified Mosher's method.