Tape casting and lamination to form Ag-sheathed (Bi,Pb)(2)Sr2Ca2Cu3O10
superconductors is investigated as an alternate manufacturing process
. Debindering the tape is a critical step which requires inhibiting vo
latile metal vaporization but allows one to control the residual carbo
n concentration. Samples may be sealed by cold pressing the oxide betw
een Ag foils, and the carbon concentration may be adjusted from 1600 t
o 350 ppm by applying an appropriate debindering schedule. The uniaxia
l pressing pressure is optimized to give the highest possible oxide co
re density of 79% without causing cracks or delamination of the compos
ite. The effects of carbon concentration and sintering time and temper
ature on J(c) are elucidated for sealed and unsealed samples. Maximum
J(c) values over 10 kA/cm(2) are found for sealed, low-carbon samples,
which is comparable to other thick film forming methods.