E. Peeters et al., PHET, AN ELECTRODELESS PHOTOVOLTAIC ELECTROCHEMICAL ETCHSTOP TECHNIQUE, Journal of microelectromechanical systems, 3(3), 1994, pp. 113-123
A novel etchstop technique for the fabrication of micromechanical comp
onents in single-crystal silicon is presented, The photovoltaic electr
ochemical etchstop technique (PHET) was characterized for anisotropic
etching in 7M KOH in the 60 degrees to 80 degrees C temperature range,
but can in principle be extended towards other anisotropic etchants,
PHET is based on the photovoltage generated across a p/n junction illu
minated during etching, In constrast with the established two-, three-
or four-electrode electrochemical etchstop on n-epi, the technique do
es not require any external electrodes or connections to be made to th
e wafer, hence alleviating the need for a mechanical etch-holder that
protects one wafer side from the etchant, These etch-holders are known
to introduce stress and to substantially reduce yield in the producti
on of the more fragile microstructures, Moreover, PHET is suited for t
he realization of diaphragm type structures in p-epi as well as for un
dercutting boron-diffused beam or bridge type of structures, In contra
st with the established high boron dose etchstop, with its known adver
se mechanical and electrical side effects, PHET does not require exces
sive boron concentrations, PHET therefore merges the fabrication possi
bilities offered by the conventional electrochemical etchstop and the
conventional high boron dose etchstop, without being subject to the re
spective drawbacks of these techniques, The only technology required i
n addition to those used in the conventional etchstops is platinum spu
ttering, The possibilities that are offered for postprocessing standar
d p-well or twin-tub CMOS substrates are considered to be a major asse
t of the presented photovoltaic etchstop. [34]