A high water holding capacity of oil sands fine tailing has been attri
buted to the presence of ultrafine ( < 0.2 mu m) clay fractions. On th
e basis of hydrophobic character two major types of ultrafines are rec
ognized: associated with a significant coverage or organic matter and
preferentially hydrophilic solids. The effect of biwetted solids on th
e colloidal stability of ultrafine clays in aqueous suspensions has be
en studied by dynamic light scattering and H-2 n.m.r. methods. The org
anic matter associates with the surfaces of the biwetted solids is bel
ieved to be responsible for their accelerating effect on aggregation.
The results indicate that prevention, or reduction, of the amount of b
iwetted solids entering the tailings pond could be beneficial.