The results of the few groups which have attempted to etch chemically
or electrochemically amorphous silicon films prepared in various ways
are reviewed briefly with a focus on the photoluminescence of such lay
ers. The particular case of plasma-deposited boron-doped hydrogenated
amorphous silicon subjected to an anodization in HF solutions followed
by an electro-oxidation in water is elucidated. Many similarities bet
ween the properties of these materials and those of their crystalline
counterparts are emphasized, but one significant difference between th
e resonantly excited PL spectra of the two porous materials is pointed
out.