R. Sugisaki et al., ACID CHARACTER OF ARCHEAN OCEAN WATERS REVEALED BY 3.3-GA-OLD FERRUGINOUS CHERT COMPOSITIONS, WESTERN-AUSTRALIA, Proceedings of the Japan Academy. Series B Physical and biological sciences, 71(6), 1995, pp. 170-174
Comparative inspection of Archean ferruginous cherts with Phanerozoic
cherts shows that the former precipitated from acid-water hydrothermal
ly supplied during intensive early Precambrian volcanism. The pH of th
e water is inferred to have been around 4 where Al dissolves, and Ti a
nd Zr do not. The peculiar geochemical environment seems to have been
widespread in Archean to early Proterozoic greenstone basins when trem
endous volume of banded iron formation (BIF) formed. This suggests tha
t the acid seas were neutralized after the BIF deposition probably dur
ing the middle to late Proterozoic; this change of pH in sea water may
have promoted the deposition of carbonate rocks.