Citation
Cs. Chin et al., FACILE INSERTION OF ALKYNES INTO IR-P (PHOSPHINE) AND IR-AS (ARSINE) BONDS - 2ND AND 3RD ALKYNE ADDITION TO MONONUCLEAR IRIDIUM COMPLEXES, Journal of the Chemical Society, Chemical Communications, (15), 1995, pp. 1495-1496
Citations number
14
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00224936
Issue
15
Year of publication
1995
Pages
1495 - 1496
Database
ISI
SICI code
0022-4936(1995):15<1495:FIOAII>2.0.ZU;2-D
Abstract
Alkynes (HC=CH, PhC=CH) insert into Ir-P (phosphine) and Ir-As (arsine
) bonds of [Ir(H)(C=CPh)(L(3))(MPh(3))](+) and [Ir-CH=CH-CH=CH)(MeCN)(
L(3))](+) in the presence of MPh(3), to produce [Ir(H)(C=CPh)(L(3)) (C
H=CHR-M(+)Ph(3))](+) and [Ir(CH=CH-CH=CH)(L(3))(CH=CHR-M(+)Ph(3))](+)
[R = H, Ph; L(3) =(CO)(PPh(3))(2);M = P, As].