SYNTHESES OF ACYLOXY CARBENE COMPLEXES M(SNPH(3))(CO)(N)(=C(OCOR)PH)(ETA-C5H5) (M=MO,W, N=2, R=ME M=FE, RU, N=1, R=ME, PH, BU(T)) AND X-RAYCRYSTAL-STRUCTURES OF FE(SNPH(3))(CO)(=C(OCOR)PH)(ETA-C5H5) (R=ME, PH)

Authors
ADAMS H MALONEY CA MUIR JE WALTERS SJ WINTER MJ
Citation
H. Adams et al., SYNTHESES OF ACYLOXY CARBENE COMPLEXES M(SNPH(3))(CO)(N)(=C(OCOR)PH)(ETA-C5H5) (M=MO,W, N=2, R=ME M=FE, RU, N=1, R=ME, PH, BU(T)) AND X-RAYCRYSTAL-STRUCTURES OF FE(SNPH(3))(CO)(=C(OCOR)PH)(ETA-C5H5) (R=ME, PH), Journal of the Chemical Society, Chemical Communications, (15), 1995, pp. 1511-1512
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
15
Year of publication
1995
Pages
1511 - 1512
Database
ISI
SICI code
0022-4936(1995):15<1511:SOACCM>2.0.ZU;2-B
Abstract
Treatment of [M(SnPh(3))(COPh)(CO)(n)(eta-C5H5)](-) (M = Fe, Ru, n = 1 ; M = Mo, W, n = 2) with acid chlorides R(1)COCl affords carbenes [M(S nPh(3))(CO)(n){C(OCOR(1))Ph}(eta-C5H5)], which in the case of the iron and ruthenium derivatives are isolable as unusually stable crystallin e solids and which react with sources of thiolate to form the new thio carbene complexes M(SnPh(3))(CO)(n){C(SR(2))Ph}(eta-C5H5).