COPPER(II) AND ZINC(II) MACROCYCLIC COMPLEXES WITH HIGH-EFFICIENCY INFIXING CO2 - CRYSTAL-STRUCTURES OF ([ZNL](3)(MU(3)-CO3))CENTER-DOT(CLO4)(4) AND ([CUL](3)(MU(3)-CO3))CENTER-DOT(CLO4)(4) (L=[15]ANEN(3)O(2))

Authors
BAZZICALUPI C BENCINI A BIANCHI A FUSI V PAOLETTI P VALTANCOLI B
Citation
C. Bazzicalupi et al., COPPER(II) AND ZINC(II) MACROCYCLIC COMPLEXES WITH HIGH-EFFICIENCY INFIXING CO2 - CRYSTAL-STRUCTURES OF ([ZNL](3)(MU(3)-CO3))CENTER-DOT(CLO4)(4) AND ([CUL](3)(MU(3)-CO3))CENTER-DOT(CLO4)(4) (L=[15]ANEN(3)O(2)), Journal of the Chemical Society, Chemical Communications, (15), 1995, pp. 1555-1556
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
15
Year of publication
1995
Pages
1555 - 1556
Database
ISI
SICI code
0022-4936(1995):15<1555:CAZMCW>2.0.ZU;2-5
Abstract
The Zn-II and Cu-II complexes with the macrocyclic ligand [15]aneN(3)O (2) (L) readily trap atmospheric CO2 to form the {[ZnL](3)(mu(3)-CO3)} .(ClO4)(4) and {[CuL](3)(mu(3)-CO3)}.(ClO4)(4) complexes, which both c ontain a triply bridging carbonate anion.