NS-CHLORO(METHYL)BIS(TRIPHENYLARSINE)PALLADIUM(II)

Authors
RATH NP LADIPO FT ANDERSON GK
Citation
Np. Rath et al., NS-CHLORO(METHYL)BIS(TRIPHENYLARSINE)PALLADIUM(II), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1289-1290
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
7
Pages
1289 - 1290
Database
ISI
SICI code
0108-2701(1995)51:<1289:N>2.0.ZU;2-D
Abstract
The title compound, [PdCl(CH3)(C18H15As)(2)], was obtained as yellow c rystals from the reaction of [PdClMe(1,5-cyclooctadiene)] with triphen ylarsine. The molecular structure is approximately square planar, with the two arsine ligands in mutually trans positions, and Pd-As distanc es of 2.3989 (5) and 2.4067(5) Angstrom, and Pd-Cl and Pd-C distances of 2.4086 (11) and 2.095 (4) Angstrom, respectively.