TRIETHYLAMMONIUM ISOPROPYL [(AMINOSULFONYL)(DIFLUORO)METHYL]PHOSPHONATE

Authors
BAENZIGER NC BURTON DJ MODA AS
Citation
Nc. Baenziger et al., TRIETHYLAMMONIUM ISOPROPYL [(AMINOSULFONYL)(DIFLUORO)METHYL]PHOSPHONATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1355-1356
Citations number
4
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
7
Pages
1355 - 1356
Database
ISI
SICI code
0108-2701(1995)51:<1355:TI[>2.0.ZU;2-Q
Abstract
The title salt, [(C2H5)(3)NH]+. C4H9F2NO5PS-, was the unexpected produ ct in an attempted synthesis of [(CH3)(2)CHO]P-2(O)CF2SO2NH2 from [(CH 3)(2)CHO]P-2(O)CF2Br and hydroxylamine-O-sulfonic acid. Both the S and P atoms are surrounded tetrahedrally, with the O-S-O and O-P-O bond a ngles of 120.7(2) and 121.4(1)degrees, respectively, showing the great est distortion from true tetrahedral geometry. The remaining bond dist ances and angles have typical values, with the bond distances to C(1), the fluorinated C atom, being slightly longer.