SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL METALLADITHIATRIAZINE CONTAINING SULFUR AND MOLYBDENUM IN HIGH OXIDATION-STATES

Authors
LUBBEN T WITT M ROESKY HW NOLTEMEYER M SCHMIDT HG
Citation
T. Lubben et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL METALLADITHIATRIAZINE CONTAINING SULFUR AND MOLYBDENUM IN HIGH OXIDATION-STATES, Inorganic chemistry, 34(16), 1995, pp. 4275-4277
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
16
Year of publication
1995
Pages
4275 - 4277
Database
ISI
SICI code
0020-1669(1995)34:16<4275:SASCOA>2.0.ZU;2-L
Abstract
The reaction of N,N-bis(trimethylsilyl)benzenesulfinamide with the chl oronitrene complex CIN=MoCl4 in a molar ratio of 2:1 leads to the nove l six-membered heterocycle 1 consisting of three nitrogen atoms, two s ulfur atoms, and one molybdenum atom. Compound 1 is the first example of a metalladithiatriazine with both the metal and the sulfur atoms in their highest oxidation states.