A possibility to build a mercury (Hg) analyzer based on the cold vapor
atomic absorption spectrometry (CVAAS) with a sub-picogram detection
limit was investigated. Construction of the gold traps and the optical
cell, carrier gas flow rate and gold traps heating power were chosen
in order to effectively concentrate sampled Hg vapor and to obtain hig
hest possible response in the optical and electronic system. The newly
created analyzer is able to detect 0.5 pg of elemental Hg vapor. Opti
mization of construction resulted in stable performance and good selec
tivity for gaseous Hg of the analyzer. The instrument is commercially
available.