Hp. Bonzel et E. Preuss, MORPHOLOGY OF PERIODIC SURFACE PROFILES BELOW THE ROUGHENING TEMPERATURE - ASPECTS OF CONTINUUM THEORY, Surface science, 336(1-2), 1995, pp. 209-224
Using a simple analytical form of the anisotropic surface free energy,
gamma(theta), the quasi-stationary shape of one-dimensional periodic
surface profiles below the roughening temperature as well as the kinet
ics of profile decay are calculated numerically. With the macroscopic
surface being close to a cusp orientation in gamma(theta), all profile
s exhibit extended flat regions at the top and bottom (facets). These
same regions and their adjacent rounded parts are near equilibrium, as
a comparison with the truncated equilibrium shape of small particles
for the same gamma(theta) shows. The facet size of the profile depends
on the total anisotropy of gamma(theta) in the zone of interest, and
on the amplitude of the profile. These dependences can also be simulat
ed by the equilibrium construction. The gamma(theta) function used in
this study is examined in relation to the more fundamental expression
for the anisotropic surface free energy and also experimental data for
Pb. It is found to fit these experimental data very well over a large
range of orientations.