STRUCTURE AND CONSTITUTION OF DICHLORO(TE TRAALKYLCYCLOBUTADIENE)PLATINUM(II) COMPLEXES

Authors
STEINBORN D GERISCH M HEINEMANN FW SCHOLZ J SCHENZEL K
Citation
D. Steinborn et al., STRUCTURE AND CONSTITUTION OF DICHLORO(TE TRAALKYLCYCLOBUTADIENE)PLATINUM(II) COMPLEXES, Zeitschrift fur anorganische und allgemeine Chemie, 621(8), 1995, pp. 1421-1425
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
8
Year of publication
1995
Pages
1421 - 1425
Database
ISI
SICI code
0044-2313(1995)621:8<1421:SACODT>2.0.ZU;2-8
Abstract
Hexachloroplatinic acid reacts in n-butanol with alkylsubstituted acet ylenes RC=CR (R = Me, Et) to give [PtCl2(C(4)R(4))] (R = Me (1), R = E t (2)). The X-ray structure analysis of 1(C2/m; a = 1370.3(2), b = 112 8.3(1), c = 691.21(7) pm, beta = 96.10(1)degrees; Z = 4) shows that 1 is monomeric and not dimeric as was described in the literature. Furth ermore, 1 and 2 were extensively studied by i. r., Raman, and n.m.r. s pectroscopical investigations.