Xw. Shi et al., DEFENSE-MECHANISMS OF ARTHROPODS .131. SPIROCYCLIC DEFENSIVE ALKALOIDFROM A COCCINELLID BEETLE, Tetrahedron, 51(32), 1995, pp. 8711-8718
A new alkaloid, chilocorine B, was characterized from a coccinellid be
etle, Chilocorus cacti. This compound represents the first spirocyclic
example of the new ''dimeric'' alkaloid family whose structures are d
erived from two thirteen-carbon tricyclic subunits, 2-methylperhydro-9
b-azaphenalene and 3,4-dimethyloctahydro-8b-azaacenaphthylene.