HIGH-PRESSURE DIELS-ALDER REACTIONS OF 2-VINYL-3,4-DIHYDRONAPHTHALENE- SYNTHESIS OF CYCLOPENTA[C]PHENANTHRENONES AND INDENO[C]PHENANTHRENONES

Authors
MINUTI L TATICCHI A GACSBAITZ E MARROCCHI A
Citation
L. Minuti et al., HIGH-PRESSURE DIELS-ALDER REACTIONS OF 2-VINYL-3,4-DIHYDRONAPHTHALENE- SYNTHESIS OF CYCLOPENTA[C]PHENANTHRENONES AND INDENO[C]PHENANTHRENONES, Tetrahedron, 51(32), 1995, pp. 8953-8958
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
32
Year of publication
1995
Pages
8953 - 8958
Database
ISI
SICI code
0040-4020(1995)51:32<8953:HDRO2>2.0.ZU;2-H
Abstract
A new shorter synthesis of 2-vinyl-3,4-dihydro-naphthalene has been de scribed. The Diels-Alder reactions of this diene with 4-acetoxy-2-cycl openten-1-one, 3-bromoindan-1-one and inden-1-one under high pressure conditions are reported. A two step synthesis of cyclopenta[c]-and ind eno[c]phenanthrenones is discussed. Structure analysis by H-1 and C-13 NMR spectroscopy is presented.