A. Guessous et al., THIN-FILMS OF CHALCOGENIDE GLASS AS SENSITIVE MEMBRANES FOR THE DETECTION OF MERCURIC IONS IN SOLUTION, Sensors and actuators. B, Chemical, 24(1-3), 1995, pp. 296-299
Thin vitreous films elaborated by microelectronic techniques can be us
ed to build up sensitive microsystems in order to detect ionic species
(Hg2+) in aqueous solution. Characteristics of sensing systems based
on thin films of chalcogenide glasses are presented. The microsensors
exhibit quasi-Nernstian potentiometric response over five orders of ma
gnitude with a limit of detection below 10(-6) mol l(-1) In the presen
ce of interfering heavy-metal ions (Pb2+, Cd2+) the sensing systems ar
e very selective, since low selectivity coefficients are obtained vers
us those ionic species.