S. Togawa et al., OXYGEN-TRANSPORT MECHANISM IN CZOCHRALSKI SILICON MELT .2. VICINITY OF GROWTH INTERFACE, Journal of the Electrochemical Society, 142(8), 1995, pp. 2844-2848
The mechanism governing oxygen transport in the vicinity of the growth
interface with varying rates of crystal rotation was investigated bot
h experimentally and computationally. Rotation induces a sweeping flow
out of-high oxygen content melt contributing to uniform radial oxygen
concentration. At low rates of rotation, low oxygen content melt flow
s into the growth interface region, rarefying the oxygen concentration
at the boule periphery and affecting the longitudinal micro-oxygen di
stribution. Calculation verified the correlation between radial veloci
ty and oxygen fluctuation, that fluctuation within the crystal is attr
ibutable to the now of low oxygen content melt from the free surface.
At higher rotational speeds, radial outflow obstructs flow from free s
urface, resulting in a relatively uniform longitudinal micro-oxygen di
stribution within the boule.