To analyse heat and mass transfer in a metal-hydrogen reactor, the fol
lowing hypotheses are typically used: (i) solid and gas are at the sam
e temperature, (ii) the effect of pressure variation in the reactor is
negligible, (iii) the effect of hydrogen concentration on the equilib
rium pressure variation is negligible. In this paper, we test the vali
dity of these hypotheses by comparing numerical results obtained with
and without these hypotheses. For a LaNi5-hydrogen reactor, the result
s show that these hypotheses are valid under almost all conditions. Co
pyright (C) 1996 International Association for Hydrogen Energy