NOVEL POLYCARBOSILAZANES WITH SI-C AND SI-N BONDS IN THE MAIN-CHAIN

Authors
BACQUE E RICHARD C PILLOT JP BIROT M DUNOGUES J PETRAUD M GERARDIN C TAULELLE F
Citation
E. Bacque et al., NOVEL POLYCARBOSILAZANES WITH SI-C AND SI-N BONDS IN THE MAIN-CHAIN, Journal of inorganic and organometallic polymers, 5(2), 1995, pp. 169-182
Citations number
39
Categorie Soggetti
Polymer Sciences
Journal title
Journal of inorganic and organometallic polymers → ACNP
ISSN journal
10530495
Volume
5
Issue
2
Year of publication
1995
Pages
169 - 182
Database
ISI
SICI code
1053-0495(1995)5:2<169:NPWSAS>2.0.ZU;2-U
Abstract
Novel polycarbosilazanes possessing Si-CH2-Si-N linkage in their backb one are described. Their preparation involves thermal cross-linking of ethyl-silylene)-co-(1,3-dimethyl-1,3-disilazane)]s at 300-350 degrees C. Thus, under controlled conditions, soluble and fusible preceramic polymers were obtained. Upon pyrolysis, these materials gave good yiel ds of silicon carbonitride-based ceramics containing low free carbon p ercentages and controlled nitrogen proportions.