The present review surveys, integrates and gives a bibliographic accou
nt of studies carried out on the degradation of butyl rubber over the
last few decades. Our objective was to extract the useful information
from such studies. As a large fraction of the related literature is in
inaccessible journals, many of which are not readily available in Eng
lish translation, this paper should help in presenting an overview and
insight into the nature of the work being done in the field. The effe
cts of thermal and thermo-oxidative conditions, mechanical stresses (d
uring processing and ultrasound treatment), catalysts, chemicals, ozon
e and radiation on the structure, and physicomechanical properties of
butyl rubber have been discussed. This rubber was chosen as a represen
tative elastomer in order to illustrate some trends in the degradation
studies of other rubbers.