Dialdehyde starches were prepared by oxidation with periodate. The inf
luence of the degree of oxidation of the dialdehyde starch on its micr
ostructural and physicochemical properties such as crystallinity, gran
ular structure, complexing capacity with iodine and lysolecithine and
water absorption are discussed. Oxidation appears to cause a gradual d
ecrease of any microstructure, meanwhile water absorption is observed
to be maximal at intermediate degrees of oxidation. A structure-swelli
ng relationship has been developed and compared with the washing effic
iency during purification.