RANDOM INTERFACE MODEL OF SPONGE PHASES

Citation
P. Pieruschka et Sa. Safran, RANDOM INTERFACE MODEL OF SPONGE PHASES, Europhysics letters, 31(4), 1995, pp. 207-212
Citations number
24
Categorie Soggetti
Physics
Journal title
ISSN journal
02955075
Volume
31
Issue
4
Year of publication
1995
Pages
207 - 212
Database
ISI
SICI code
0295-5075(1995)31:4<207:RIMOSP>2.0.ZU;2-B
Abstract
We present a coherent structural and thermodynamic approach to sponge phases of surfactant solutions based on the curvature energy of the su rfactant film characterized by the bending moduli kappa, <(kappa)over bar>, the surfactant concentration phi(S) and the inside/outside ratio phi. We find that an entropy-driven transition between symmetric (S) and asymmetric (A) sponge phases with a critical phi(B) similar to kap pa(-1/3) is possible. Film and bulk scattering are given consistently, in terms of the correlation length xi(kappa, <(kappa)over bar>, phi(S )) and the structural wave vector k(0)(kappa, <(kappa)over bar>, phi(S )). The film scattering at small wave vectors has approximately an arc tangent form and-depending on the value of k(0) xi- more or less prono unced irregularity at about 2k(0).